SODIUM BISMUTHATE

Safety Data Sheet
Emergency Telephone Number: CHEMTREC 1-800-424-9300       For Information call: DUDLEY 732-886-3100       
      DUDLEY CORPORATION
           	125 Kenyon Drive
       				         	 Lakewood, New Jersey 08701
Effective Date: January 1, 2025	
1. PRODUCT:	CAS No.: 12232-99-4    E-C No.:235-455-6	Weight:  279.97g/mol 	Formula: BiNaO3

2. HAZARDS: GHS:  Acute toxicity, Oral (Category 4)		
 Pictogram: 					
Signal Word:         WARNING
HAZARD STATEMENT(S): H302: Harmful if swallowed
PRECAUTIONARY STATEMENT(S) : P264: wash skin thoroughly after handling
P270: Do not drink, eat, smoke, when using this product.	P330: Rinse mouth
P501: Dispose of contents/container to an approved waste disposal plant.

HMIS: Health hazard  2, Flammability   0,  Physical hazards   0			
NFPA Rating: Health hazard  2, Fire     0, Reactivity hazard   0

Potential Effects: Eye: Risk of serious damage to eyes.	Skin: Harmful in contact with skin. Ingestion: Harmful if swallowed. 		Inhalation: Harmful by inhalation. 
2.3: Other Hazards: none

3. COMPOSITION, INFO:
Chemical Name 			CAS No.		Percent			Hazardous
Sodium Bismuthate		12232-99-4	~80%			      No

4. FIRST AID: Eyes: rinse with plenty of water. Skin:. Rinse with plenty of soap & water Ingestion: Do not induce vomiting without medical advice. Rinse with water. Inhalation: Move to fresh air.  Physician: Treat symptomatically and supportively. 

5. FIRE FIGHTING: Info: Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH & PPE. Irritating & highly toxic gases may be generated by thermal decomp or combustion.  Runoff from fire control or dilution water may cause pollution.	Extinguishing: use dry chemical, carbon dioxide or alcohol-resistant foam. Hazards: Sodium & Bismuth oxides. Flash Pt: N/A Auto-ignition Temp: N/A Explosion Limits: N/A

6. ACCIDENTAL RELEASE: Info: Use proper PPE as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation.  Do Not get water inside containers.2

7. HANDLING & STORAGE: Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas/contact with eyes, skin, and clothing. Do not ingest or inhale.  Do not allow contract with water.  Keep from contact with moist air and steam.  Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatibles. Store protected from moisture.

8. EXPOSURE: Facilities storing or utilizing this material should be equipped with an eyewash facility and safety shower. Use adequate ventilation to keep airborne concentrations low.
Chemical				ACGIH		NIOSH		OSHA - Final / Vacated PEL’s
Sodium Bismuthate			None listed	None listed	None listed

PPE: Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear Appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. 

9. PHYSICAL & CHEM: Color: Yellow to brown powder

10. STABILITY & REACTIVITY: Avoid: Incompatibles, light, dust generation, moisture. Stability: Stable at room temp in closed containers under normal storage/handling conditions.  Incompatibilities:   Moisture	Hazardous Decomp. Products: see section 5

11. TOXICOLOGICAL INFO: RTECS: VZ1750000	LD50/LC50:  LD50 Oral rat – 420mg/kg
Carcinogencity: CAS# 12232-99-4 Sodium Bismuthate: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.  

12. ECOLOGICAL INFO: Environmental Fate/Toxicity: No information found.

13. DISPOSAL CONSIDERATIONS: Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. Empty containers must be decontaminated before returning for recycling. 
RCRA P-Series: None listed. RCRA U-Series: None listed. 

14. TRANSPORT INFO: No info available. 

15. REGULATORY INFO: SARA 311/312: Acute Health Hazard
Section 302None of the chemicals in this product have a TPQ/RQ. 
Section 313 No chemicals are reportable under Section 313. 
STATE is not present on state lists from CA, MN, MA, FL. 
PA Right to Know:	Bismuth sodium trioxide CAS#12232-99-4      NJ Right to Know: Bismuth sodium trioxide CAS#12232-99-4
California Prop.65 components: None of the chemicals are known to cause cancer, birth defects, or any other reproductive harm.

EUROPEAN/INTERNATIONAL REGULATIONS European Labeling in Accordance with EC Directives 
Hazardous Symbols: XN WGK (Water Danger/Protection) CAS# 12232-99-4: No information available. 
Canada - DSL/NDSL CAS# 12232-99-4 is listed on Canada’s DSL List. 
Canada - WHMIS: is not available. CAS# 12232-99-4 is not listed on Canada’s Ingredient Disclosure List. 

16. DISCLAIMER INFO: DUDLEY CORPORATION provides the information herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this  Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. DUDLEY CORPORATION makes no representations or warranties, either expressed or implied, including without limitation and warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly,  DUDLEY CORPORATION will not be responsible for damages resulting from the use of or reliance upon this information.