SALICYLAMIDE

Safety Data Sheet
Emergency Telephone Number: CHEMTREC 1-800-424-9300       For Information call: DUDLEY 732-886-3100
      DUDLEY CORPORATION
           	       125 Kenyon Drive
       				         	       Lakewood, New Jersey 08701
Effective Date: January 1, 2025	
1. PRODUCT ID:  Syn:  2-Hydroxybenzamide 	CAS No.: 65-45-2 E-C No.:200-609-3	Weight:  137.14g/mol 	                                  Formula: C7H7NO2

2. HAZARDS ID: GHS Classification:  Acute toxicity, Oral (Category 4) Skin irritation (Category 2)
Eye irritation (Category 2A)		 Specific target organ toxicity - single exposure (Category 3)
 Pictogram: 				                  
Signal Word:         WARNING
HAZARD STATEMENT(S): H302: Harmful if swallowed. 	H319: Causes serious eye irritation.	
	H315: Causes skin irritation.	H335: May cause respiratory irritation.	
PRECAUTIONARY STATEMENT(S) : P261: Avoid breathing dust/spray/ fume/gas/ mist/ vapors.  P330: Rinse mouth
P264: Wash skin thoroughly after handling   P270: Do not drink, eat, smoke, when using this product.
P271: Use only outdoors or in well-ventilated area.  P405: Store locked up.  P280: Wear protective gloves/eye & face protection	
P301 + P312: If Swallowed: Call Poison Center or doctor/physician if you feel unwell
P304 + P340: If inhaled: remove to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: If in Eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present & 
easy to do so. Continue rinsing.  P312: Call Poison Center or doctor/physician if you feel unwell.
P322: Specific measures (see supplemental first aid instructions)  
P332 + P313: If skin irritation occurs: consult physician   P337 + P313: If eye irritation occurs: consult physician
P362: Take off contaminated clothing and wash before reuse. P302 + P352: If on skin gently wash with plenty of soap & water.  	P403 + P233: Store in a well- ventilated place. Keep container tightly closed.
P501: Dispose of contents/container to an approved waste disposal plant.

HMIS Classification: Health hazard  2, Flammability   0,  Physical hazards   0			
NFPA Rating: Health hazard  2, Fire     0, Reactivity hazard   0

Potential Effects: Eye: Risk of serious damage to eyes.	Skin: Harmful in contact with skin. 
	               Ingestion: Harmful if swallowed. 	Inhalation: Harmful by inhalation. 
2.3: Other Hazards: none

3. COMPOSITION / INFO ON INGREDIENTS: 
Chemical				    	 CAS No.	   	Percent  		Hazardous
Salicylamide				 65-45-2                     ~ 99%                             No 	

4. FIRST AID: Eyes: Rinse immediately for 15 min. with plenty of water and seek medical advice. 
Skin: Rinse with plenty of soap & water and seek medical advice. Ingestion: Do not induce vomiting without medical advice. Rinse with water. Consult physician. Inhalation: Move to fresh air.  Consult a physician. Physician: Treat symptomatically & supportively. 

5. FIRE FIGHTING: Info: Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH & full PPE. Dusts at sufficient concentrations can form explosive mixtures with air. Irritating & highly toxic gases may be generated by thermal decomp/combustion. Hazards: Carbon & Nitrogen oxides. Extinguishing: Use dry chem, carbon dioxide, water spray or alcohol-resistant foam. Flash Pt: N/A Auto-ignition Temp: N/A 	Explosion Limits, Lower: N/A 

6. ACCIDENTAL RELEASE: Info: Evacuate area. Use proper PPE as indicated in Section 8. 
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation.  

7. HANDLING & STORAGE: Handling: Do not breathe dust. Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Storage: Keep away from sources of ignition. Do not store in direct sunlight. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.  Keep containers tightly closed.

 
8. EXPOSURE CONTROLS: 
Chemical				ACGIH		                NIOSH		
Salicylamide			None listed 		None listed

PPE: Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure.  0.11mm thick nitrile. Clothing: Wear appropriate protective clothing to prevent skin exposure. 
Respirators: A respiratory protection program that meets OSHA’s 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard En 149 must be followed whenever workplace conditions warrant a respirator’s use. 

9.PHYSICAL & CHEM: Physical State: Solid. MP: 139–144°C (282-291˚F)  

10. STABILITY & REACTIVITY: Stability: Stable under normal temperatures and pressures. Moisture sensitive. Light sensitive. Darkens on exposure to light. Avoid: High temperatures, incompatibles, light, moisture, strong oxidants, strong bases. Incompatibilities: Oxidizing agents, lead acetate, iron salts, alkalis, iodine, spirit nitrous ether. 
Haz Decomp: see section 5

11.TOXICOLOGICAL INFO: RTECS#: VN6475000. 
LD50/LC50: Oral, rat 980 mg/kg LD50. Remarks: Behavioral: Somnolence. Respiratory depression.
Irritation Data:  Eyes: Rabbit, 100 mg, 24H, Remarks: Moderate irritation effect. 
Carcinogenicity: Salicylamide is not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Reproductive Effects:  Rat, Effects on fertility: Post-implantation mortality. Specific Developmental Abnormalities: Musculoskeletal system. Hamster, preg, effects on fertility: post implantation mortality. 

12. ECOLOGICAL INFO: Ecotoxicity:   LC50-fathead minnow-101mg/l-96h  

13. DISPOSAL CONSIDERATIONS: Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.  RCRA P-Series: None listed.  RCRA U- Series: None listed. 

14. TRANSPORT REGULATIONS: Not regulated. 

15. REGULATORY INFO: SARA 311/312:  Acute & Chronic Health Hazard.
Section 302 (RQ & TPQ) None of the chemicals in this material have an RQ & TPQ. 
Section 313 No chemicals are reportable under Section 313. 

STATE CAS# 135-49-9  is not present on state lists from CA, MN, MA, FL. 
Pa Right to Know:	Salicylamide  CAS#65-45-2		NJ Right to Know:	Salicylamide  CAS#65-45-2
California Prop.65 components: None of the chemicals are known to cause cancer, birth defects, or any other reproductive harm.

EUROPEAN/INTERNATIONAL REGULATIONS European Labeling in Accordance with EC Directives 
Hazard Symbols: XN. 
Canada – DSL: CAS# 65-45-2 is listed on Canada’s DSL List.  NDSL:  CAS# 65-45-2 is not listed on Canada’s NDSL list
Canada - WHMIS This product has been classified in accordance with the hazard criteria of the CPR, and the MSDS contains all the information required by the CPR. 

16. DISCLAIMER INFO: DUDLEY CORPORATION provides the information herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. DUDLEY CORPORATION makes no representations or warranties, either expressed or implied, including without limitation and warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, DUDLEY CORPORATION will not be responsible for damages resulting from the use of or reliance upon this information.