NICKEL II BROMIDE ANHYDROUS

Safety Data Sheet
Emergency Telephone Number: CHEMTREC 1-800-424-9300       For Information call: DUDLEY 732-886-3100       
      DUDLEY CORPORATION
           	     125 Kenyon Drive
       				         	     Lakewood, New Jersey 08701
Effective Date: January 1, 2025	
1. PRODUCT ID:  CAS No.: 13462-88-9       E-C No.:236-665-0 Weight:  218.50g/mol 	Formula: Br2Ni

2. HAZARDS ID: GHS Classification: Acute aquatic toxicity (Category 1) Germ cell Mutagenicity(Cat2)
Respiratory sensitization (Category 1) Chronic aquatic toxicity (Category1) Skin sensitization (Category1) Reproductive toxicity, (Category1B)  Carcinogenicity (Category 1B)Specific target organ toxicity - repeated exposure (Category 1)
 Pictogram: 				         
Signal Word:         DANGER
HAZARD STATEMENT: H317: May cause allergic skin reaction H350: May cause cancer. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H341: Suspected of causing genetic defects. H360: May damage fertility or the unborn child. H372: Causes damage to organs through prolonged or repeated exposure if inhaled.	
H410: Very toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENT: P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P260: Do not breathe dust/fume/gas/mist/vapors/spray. P264: wash skin thoroughly after handling. P270: Do not drink, eat, smoke, when using this product.     P273: Avoid release into environment P272: Contaminated work clothes should not be allowed out of the workplace. P405: Store locked up.
P280: Wear protective gloves/eye & face protection. P285: Wear respiratory protection. P302 + P352: If on skin gently wash with plenty of soap & water. P308 +P313: If exposed or concerned: contact doctor/physician.  P363: Wash contaminated clothing before reuse. P333 + P313: If skin irritation or rash occurs: consult physician.   
P304 + P341: If inhaled: If breathing is difficult remove to fresh air & keep at rest in a position comfortable for breathing.
P391: Collect spillage.  P501: Dispose of contents/container to an approved waste disposal plant.

HMIS Classification: Health hazard  2, Flammability   0,  Physical hazards   0			
NFPA Rating: Health hazard  0, Fire     0, Reactivity hazard   0
2.3: Other Hazards: none

3. COMPOSITION / INFO: 
Chemical Name						 CAS No.	 	Percent		
Nickel dibromide  						13462-88-9  	90-100% 

4. FIRST AID: Eyes: Rinse immediately with plenty of water and seek medical advice. Skin: Rinse with plenty of soap & 
water Ingestion: Do not induce vomiting without medical advice. Rinse with water. Inhalation: Move to fresh air.  
Physician: Treat symptomatically & supportively.

5. FIRE FIGHTING: Info: Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH & full PPE.   Runoff from fire control or dilution water may cause pollution. Substance is noncombustible. Hazards: Hydrogen Bromide gas, Nickel oxides. Extinguishing:  Use water spray, dry chemical, carbon dioxide, or alcohol-resistant foam.	

6. ACCIDENTAL RELEASE: Info: Use proper PPE as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the PPE sect. Avoid generating dusty conditions. Provide ventilation. Do not let this enter the environment.

7. HANDLING & STORAGE: Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.  Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.   Hygroscopic.

8. EXPOSURE: Facilities storing or utilizing this material should be equipped with an eyewash facility and safety shower. Use adequate ventilation to keep airborne concentrations low.
Chemical 		ACGIH	        	NIOSH	                                	OSHA 		CA
Nickel (II) bromide		None listed	0.015 mg/m3 TWA 		1 mg/m3 TWA	 0.05mg/m3 PEL

PPE: Eyes: Wear protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. 0.11mm thick nitrile. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. 

9. PHYSICAL & CHEM: Appearance: Brown powder Melting Pt: 963C (1,765˚F) Relative Density: 5.098 g/cm3 at 25˚C

10. STABILITY & REACTIVITY: Stability: Stable at room temp in closed containers under normal storage and handling conditions. Hygroscopic: Absorbs moisture or water from the air. Incompatibilities: Strong oxidizing agents, strong acids, sulfur, potassium, selenium. Haz Decomp: see section 5

11. TOXIC INFO: RTECS: unlisted LD50/LC50: N/A Carcinogenicity:  Not listed by ACGIH, NIOSH, or OSHA.  Studies: Stomach irregularities IARC Group 1- Carcinogenic to humans (Nickel dibromide)   NTP: known to be human carcinogen

12. ECOLOGICAL INFO: Fate: Very toxic to aquatic life with long lasting effects.

13. DISPOSAL CONSIDERATIONS: Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste.US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. 
RCRA P-Series: None listed. 	RCRA U-Series: None listed. 

14. TRANSPORT INFO: DOT:  Not Regulated
IMDG: UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., (Nickel dibromide), 9, III,		

IATA: UN 3077, Environmentally hazardous substance, solid, n.o.s., (Nickel dibromide), 9, III,

15. REGULATORY INFO: SARA 311/312: Acute Health Hazard, Chronic Health Hazard 

SARA Section 302 Extremely Hazardous Substances None of the chemicals in this product have a TPQ/RQ.
Section 313 This material contains Nickel dibromide CAS#13462-88-9 Rev. 12/1/1989 which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. 
STATE CAS# 13462-88-9 is not present on state lists from CA, MN, MA, FL. 
PA & NJ Right to Know: Nickel dibromide CAS#13462-88-9 Rev. 07/08/2015
California Prop 65 WARNING: This product contains Nickel (II) bromide, listed as ‘Nickel compounds’, a chemical known to the state of California to cause cancer. Nickel dibromide CAS#13462-88-9 Rev. 12/1/1989
EUROPEAN/INTERNATIONAL REGULATIONS European Labeling in Accordance with EC Directives 
Hazardous Symbols:   T N     WGK (Water Danger/Protection) CAS# 13462-88-9: No information available.
Canada - DSL/NDSL: is listed on Canada’s NDSL List. 
Canada – WHMIS:  (listed as Nickel soluble compounds) is listed on Canada’s Ingredient Disclosure List. 

16. DISCLAIMER INFO: DUDLEY CORPORATION provides the information herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this.  Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. DUDLEY CORPORATION makes no representations or warranties, either expressed or implied, including without limitation and warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, DUDLEY CORPORATION will not be responsible for damages resulting from the use of or reliance upon this information.