METHYL VIOLET 2B

Safety Data Sheet
Emergency Telephone Number: CHEMTREC 1-800-424-9300       For Information call: DUDLEY 732-886-3100       
      DUDLEY CORPORATION
           	        125 Kenyon Drive
       				         	        Lakewood, New Jersey 08701
Effective Date: January 1, 2025	
1. PRODUCT ID: Syn:  C.I. Basic Violet 1    CAS No.: 8004-87-3  

2. HAZARDS ID: GHS Classification: Acute aquatic toxicity (Category 1)   Acute toxicity, Oral (Category 4)	 
Chronic aquatic toxicity (Category 1) Carcinogenicity (Category 2)  Serious eye Damage (Category 1)
 Pictogram: 				
Signal Word:         DANGER
HAZARD STATEMENT(S): H302: Harmful if swallowed. 	 H351: Suspected of causing cancer.		
H410: Very toxic to aquatic life with long lasting effects.   H318: Causes serious Eye damage. 
PRECAUTIONARY STATEMENT(S) : P201: Obtain special instructions before use. P202: Do not handle until all safety 
precautions have been read and understood. P330: Rinse mouth. P264: wash skin thoroughly after handling. P270: Do 
not drink, eat or smoke, when using this product.  P273: Avoid release into environment.  P405: Store locked up. 
P280: Wear personal protection as required. P301 + P312: If Swallowed: Call Poison Center or doctor/physician if you feel unwell. P305 + P351 + P338 + P310: If In eyes: Rinse Cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call doctor. P308 +P313: If exposed or concerned: contact doctor/physician. P391: Collect spillage. P501: Dispose of contents/container to an approved waste disposal plant.

HMIS Classification: Health hazard  2, Flammability   0,  Physical hazards   0			
NFPA Rating: Health hazard  2, Fire     0, Reactivity hazard   0
2.3: Other Hazards: none

3. COMPOSITION / INFO: 
Chemical Name					 CAS No.	 	Percent		
C.I. Basic Violet					 8004-87-3  	90-100% 

4. FIRST AID: Eyes: Rinse immediately with plenty of water for 15 min. and seek medical advice. 
Skin: Rinse with plenty of soap & water and seek medical advice. Ingestion: Do not induce vomiting without medical advice. Rinse with water. Inhalation: Move to fresh air.  Physician: Treat symptomatically & supportively.
 
5. FIRE FIGHTING: Info:  Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH & full PPE.  Irritating & highly toxic gases may be generated by thermal decomp/combustion.  Specific Hazards:  Unknown   
Extinguishing: Use dry chemical, CO2, water spray or alcohol resistant foam.                                                

 6. ACCIDENTAL RELEASE: Info: Use proper PPE as indicated in Section 8. Spills/Leaks:  Clean up spills immediately, observing precautions in the PPE section. Vacuuming or wet sweeping may be used to avoid dust dispersal. Provide ventilation.

7. HANDLING & STORAGE: Handling:  Wash thoroughly after handling.  Use with adequate ventilation.  Minimize dust generation and accumulation.  Avoid contact with eyes, skin and clothing.  Avoid ingestion and inhalation. 
Storage:  Store in a cool, dry ventilated area.  Keep containers tightly closed.
  
8. EXPOSURE CONTROLS / PPE:  Facilities storing or utilizing this material should be equipped with and eyewash facility and safety shower.  Use adequate ventilation to keep airborne concentrations low.

Chemical Name				ACGIH		NIOSH		OSHA-Final /Vacated PEL’s
Methyl Violet				None listed	None listed	None listed

PPE: Eyes:  Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin:  Wear appropriate protective gloves. 0.11mm thick nitrile. Clothing:  Wear appropriate protective clothing to prevent skin exposure. Respirators:  Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. 

9. PHYSICAL & CHEM: Appearance: Blue green crystals.  Melting Pt: 137C (279F) 

10. STABILITY & REACTIVITY: Stability: Stable under ordinary conditions of use & storage. Avoid:  Incompatibles, dust generation, excess heat, strong oxidants. Incompatibilities:  Strong oxidizers. Haz Decomp: see section 5
  
11. TOXICOLOGICAL INFO: RTECS#GC8425000	LD50/LC/50: Oral, rat:  LD50 = 4l3 mg/kg
Carcinogenicity:  Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.

12. ECOLOGICAL INFO: Fate: Very toxic to aquatic life.  
Toxicity: LC50 Fathead minnow-0.047mg/l-96h  LC50-Water flea-420 mg/l-48h  

13. DISPOSAL CONSIDERATIONS: Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste.  US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.  Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series:  None listed	RCRA U-Series:  None listed.

14. TRANSPORT REGULATIONS:  DOT: Not regulated
IMDG: UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Methyl Violet), 9, III   EMS-No: F-A, S-F     
Marine Pollutant 
IATA: UN 3077, Environmentally Hazardous substance, solid, n.o.s. (Methyl violet), 9, III,   

15. REGULATORY INFO: SARA 311/312: Acute Health Hazard / Chronic Health Hazard
SARA Section 302 Extremely Hazardous Substances. None of the chemicals in this product have a TPQ/RQ.
Section 313: No chemicals are reportable under Section 313.
STATE:	is not present on state lists from CA,  MN, MA, FL.
PA & NJ Right to Know: C.I. Basic Violet 1 CAS#8004-87-3 
California No Significant Risk Level:  None of the chemicals in this product are listed.

EUROPEAN/INTERNATIONAL REGULATIONS European Labeling in Accordance with EC Directives
Hazard Symbols:    XN 	WGK (Water Danger/Protection): No information available.
Canada – DSL/NDSL:  CAS#8004-87-3 is listed on Canada’s DSL List.
Canada – WHMIS:	 CAS# 8004-87-3  No information available.
CAS# 8004-87-3 is not listed on Canada’s Ingredient Disclosure List.

16. DISCLAIMER INFO: DUDLEY CORPORATION provides the information herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this.  Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. DUDLEY CORPORATION makes no representations or warranties, either expressed or implied, including without limitation and warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, DUDLEY CORPORATION will not be responsible for damages resulting from the use of or reliance upon this information.