LEAD NITRATE ACS

Safety Data Sheet
Emergency Telephone Number: CHEMTREC 1-800-424-9300       For Information call: DUDLEY 732-886-3100       
      DUDLEY CORPORATION
           	       125 Kenyon Drive
       				         	       Lakewood, New Jersey 08701
Effective Date: January 1, 2025	
1. PRODUCT: CAS No.: 10099-74-8 E-C No.:233-245-9 Weight:331.21g/mol Formula: N2O6Pb

2. HAZARDS: GHS Class: Oxidizing solids (Cat 2) Serious eye damage (Cat 1) Acute toxicity, Inhalation (Cat 4)   Reproductive toxicity (Cat 1A)  Carcinogenicity (Cat 1B) Acute toxicity, Oral (Cat 4)   Acute aquatic toxicity (Cat 1) Chronic aquatic toxicity (Cat 1) Specific target organ toxicity - repeated exposure (Cat 1) Blood Central Nervous system Immune system, kidney. Skin sensitization (Cat. 1)
 Pictogram: 		                                                   
Signal Word:         DANGER
HAZARD STATEMENT: H302 + H332: Harmful if swallowed, or inhaled. H317: May cause an allergic skin reaction. 	H272: May intensify with fire.; oxidizer. H318: Causes serious eye damage.  H350: May cause cancer. H360: May damage fertility or unborn child.	 H410: Very toxic to aquatic life with long lasting effects. H372: Causes damage to organs (Blood, Central Nervous System, Immune System, Kidney) through prolonged or repeated exposure. 	
PRECAUTIONARY STATEMENT: P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat. P220: Keep/Store away from clothing/combustible materials.  P391: Collect spillage. P221: Take precaution to avoid mixing with combustibles.  P270: Do not drink, eat, smoke, when using this product. P260: Do Not breathing dust/spray/ fume/gas/ mist/ vapors. P264: Wash skin thoroughly after handling.	
P271: Use only outdoors or in well-ventilated area. P405: Store locked up. P330: Rinse mouth.  P280: Wear protective gloves/eye & face protection.	P273: Avoid release into the environment. P301 + P312:If Swallowed: Call Poison Center or doctor/physician if you feel unwell. P304 + P340: If inhaled: remove to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: If in Eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present & 
easy to do so. Continue rinsing. P310: immediately call a Poison center or doctor/physician. P501: Dispose of contents/container to an approved waste disposal plant. P302 + P352: If On Skin: Wash with plenty of soap and water. P501: Dispose of contents / container to an approves waste disposal plant. 

HMIS Class: Health hazard  2, Flammability   0,  Physical hazards  2			
NFPA Rating: Health hazard  2, Fire     0, Reactivity hazard   2   Special Hazard: OX
2.3: Other Hazards: none

3. COMPOSITION / INFO ON INGREDIENTS: 
Chemical 				 CAS No.	 	Percent		
Lead nitrate		                10099-74-8                99-100%                  

4. FIRST AID: Eyes: Rinse immediately with plenty of water for 15 min and seek medical advice.  Skin: Rinse with plenty of soap & water and seek medical advice. Ingestion: Do not induce vomiting without medical advice. Rinse with water. Consult physician. Inhalation: Move to fresh air.  Consult a physician. Physician: Treat symptomatically & supportively. 

 5. FIREFIGHTING: Info:  Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH, & full PPE.  Strong Oxidizer.  Contact with other material may cause fire. Irritating & highly toxic gases may be generated by thermal decomp/combustion. Hazards:  Nitrogen & Lead oxides. Extinguishing:  Use Dry sand, dry chem.

6. ACCIDENTAL RELEASE: Info:  Use proper PPE as indicated in Section 8. Spills/Leaks:  Vacuum or sweep up material and place into a suitable disposal container.  Avoid generating dusty conditions.  Provide ventilation.  Keep combustibles (wood, paper, oil, etc.,) away from spilled material. Do not let this product enter drains. 

7.  HANDLING & STORAGE: Handling:  Wash thoroughly after handling.  Remove contaminated clothing and wash before reuse.  Use with adequate ventilation.  Minimize dust generation and accumulation.  Avoid contact with eyes, skin, and clothing. Storage:  Keep in a tightly closed container. Store in a cool, dry, ventilated area away from sources of heat or ignition.  Do not store near combustible materials.  Keep away from reducing agents, and out of direct sunlight. 

8. EXPOSURE:  Facilities storing or utilizing this material should be equipped with any eyewash facility and safety shower.  Use local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits.
Chemical 			ACGIH			NIOSH		         OSHA-Final PEL’s
			       0.05 mg/m3 TWA (as Pb)	0.050 mg/m3 TWA          0.05 mg/m3 TWA (as Pb);	
Lead nitrate		      (listed under Lead, inorganic           (as Pb) (listed under         30aeg/m3 Action Level (as Pb                                                       	      compounds).                                    Lead compounds).         Poison – see 29 CFR 1910.10  25   
  	
OSHA Vacated PELs:  Lead nitrate:  No OSHA Vacated PELs are listed for this chemicals
PPE: Eyes:  Wear appropriated protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin:  Wear appropriated gloves to prevent skin exposure. 0.11mm thick nitrile. 
Clothing:  Wear impervious protective clothing, including boots, gloves, lab coat,  apron or coveralls, to prevent skin exposure.
Respirators:  Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149.  Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.  Refer two 29 CFR 1910.1025 for regulations on respiratory protection required during exposure to lead and lead compounds. Hygiene: Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

9.  PHYSICAL & CHEM:  Appearance: White crystalline powder.  Odor: Odorless.  Relative Density: 4.77 g/cm3  Melting Pt: 470˚C (878˚F) Solubility:  486 g/l at 20°C pH: 3-4 at 50 g/l at 20°C Boiling Pt.: >500°C at 1,013 hPa-OECD Test Guideline 103 Auto-ignition temp: 400°C NF T 20-036 Vapor Pressure at 20C 104 low

10. STABILITY & REACTIVITY: Stability: Stable under ordinary conditions of use & storage. Avoid: Dust generation, excess heat, and incompatibles. Incompatibilities: Strong reducing agents, organic materials & powdered metals. Haz Decomp: see section 5 

11. TOXICOLOGICAL INFO: RETCS#  OG2100000  LD50:  Rat Dermal >2,000 mg/kg. Carcinogenicity:  ACGIH: A3- Confirmed animal carcinogen with unknown relevance to humans NTP: Suspect carcinogen (listed as Lead compounds). IARC: Group 2A - Possibly carcinogenic to humans      Stomach irregularities with Human Evidence. 
Reproductive Effects:  Toxicant central nervous system  Neurotoxicity:  Repeated exposure neurological changes.

12. ECOLOGICAL INFO:  Fate: Marine pollutant. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.    Toxicity: Toxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) – 0.1 mg/l - 96 h
LC50 - Algae – 0.24 – 0.29 mg/l - 28 h
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) – 1.8 mg/l - 48h

13.  DISPOSAL CONSIDERATIONS: Chemicals waste generators must determine whether a discarded chemicals is classified as a hazardous water.  US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.  Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series:  None listed U-Series:  None listed.

14.  TRANSPORT INFO: RQ 10 lbs. or 4.54 kg.    DOT: UN 1469, Lead nitrate, 5.1, (6.1), II, ERG 141	
IMDG: UN 1469, LEAD NITRATE, 5.1, (6.1), II     MARINE POLLUTANT
IATA: UN 1469, Lead nitrate, 5.1, (6.1), II 

15.  REGULATORY INFO: Sara 311/312: Reactivity, Acute Health hazard, Chronic Health Hazard
CERCLA Hazardous Substances RQ’s: 10 lb final RQ; 4.54 kg final RQ.  SARA Section 302: No TPQ.
Section 313:  This material contains Lead nitrate (listed as Lead, inorganic compounds), >99%, (CAS#10099-74-8) which is subject to the reporting requirements of Section 313 of  SARA Title III and 40 CFR Part 373.
STATE: CAS#10099-74-8  is not present on state lists from CA, MN, MA, FL. 
Mass / PA/ NJ Right to Know:	Lead nitrate  CAS#10099-74-8 Rev. 04/24/93
California Prop.65: WARNING! This product contains a chemical known to the state of CA to cause cancer. Lead (III)carbonate  CAS#10099-74-8 Rev. 04/24/93

European Labeling in Accordance with EC Directives – Restricted to professional users. 
WGK (Water Danger/Protection):  CAS#10099-74-8:  2
Canada – DSL/NDSL:  CAS#10099-74-8 is listed on Canada’s DSL List.
Canada – WHMIS:  This product has a WHMIS classification of C, D2A.
Canadian Ingredient Disclosure List: CAS#10099-74-8 is listed on Canadian Ingredient Disclosure List.

 
16. DISCLAIMER INFO: DUDLEY CORPORATION provides the information herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this.  Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. DUDLEY CORPORATION makes no representations or warranties, either expressed or implied, including without limitation and warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, DUDLEY CORPORATION will not be responsible for damages resulting from the use of or reliance upon this information.