3-HYDROXYPICOLINIC ACID

Safety Data Sheet
Emergency Telephone Number: CHEMTREC 1-800-424-9300       For Information call: DUDLEY 732-886-3100       
      DUDLEY CORPORATION
           	125 Kenyon Drive
       				         	 Lakewood, New Jersey 08701
Effective Date: January 1, 2025	
1. PRODUCT: Syn:  3-HPA, 3-Hydroxypyridine-2-carboxylic acid CAS No.: 874-24-8 E-C No.:212-859-0
Weight:  139.11g/mol 	Formula: C6H5NO3

2. HAZARDS: GHS Class:   Skin irritation (Category 2)	Eye irritation (Category 2A)		
			   Specific target organ toxicity - single exposure (Category 3)
 Pictogram: 					
Signal Word:         WARNING
HAZARD STATEMENT:H319: Causes serious eye irritation. H315: Causes skin irritation H335: May cause respiratory irritation	
 PRECAUTIONARY STATEMENT: P261: Avoid breathing dust/spray/ fume/gas/ mist/ vapors. P264: wash skin thoroughly after handling	P271: Use only outdoors or in well-ventilated area. P405: Store locked up.	P280: Wear protective gloves/eye & face protection. P302 + P352: If on Skin wash with plenty of soap & water. P304 + P340: If inhaled: remove to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: If in Eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present & easy to do so. Continue rinsing. P312: Call Poison Center or doctor/physician if you feel unwell. P321: Specific treatment (see supplemental first aid instructions).
P332 + P313: If skin irritation occurs: consult physician  P337+P313: If eye irritation occurs: consult physician.
P362: Take off contaminated clothing and wash before reuse. P403 + P233: Store in a well ventilated place. Keep container tightly closed. P501: Dispose of contents/container to an approved waste disposal plant.

HMIS Class: Health hazard  2, Flammability   0,  Physical hazards   0			
NFPA Rating: Health hazard  2, Fire     0, Reactivity hazard   0
2.3: Other Hazards: none

3. COMPOSITION / INFO ON INGREDIENTS: 
Chemical 					 CAS No.	 	Percent		
3-Hydroxypyridine-2-carboxylic acid	                874-24-8               98%                  

4. FIRST AID: Eyes: rinse for 15 min. with plenty of water and seek medical advice. Skin: Rinse with plenty of soap & water and seek medical advice. Ingestion: Do not induce vomiting without medical advice. Rinse with water. Consult physician. Inhalation: Move to fresh air.  Consult a physician. Physician: Treat symptomatically & supportively. 

5. FIREFIGHTING: Info: wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH & full PPE. Irritation & toxic gases may be generated by thermal decomp/combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Extinguishing: Use water spray, dry chem, carbon dioxide, or alcohol-resistant foam. Hazards: Carbon & Nitrogen oxides. Flash Pt: N/A. Auto-ignition Temp: N/A. Explosion Limits: N/A. 

6. ACCIDENTAL RELEASE: Info: Use proper PPE as indicated in Section 8. Spills/Leaks: Clean up spills immediately, observing precautions in the PPE Sec. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. 

7.  HANDLING & STORAGE:  Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse. Storage: Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.  Non-combustibles.

8. EXPOSURE: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. 
Chemical 	                           ACGIH                     NIOSH                    OSHA-Final / Vacated PELs 
3-Hydroxy-Picolinic Acid           None listed             None listed           None listed

PPE: Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. 0.11mm thick nitrile. Clothing: Wear appropriate protective clothing to prevent skin exposure. 
Respirators: follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. 

9.  PHYSICAL & CHEM: State: Crystalline powder. Beige. Melting Pt: 213-218˚C (415-424˚F)

10. STABILITY & REACTIVITY: Stability: Stable at room temp in closed containers under normal storage & handling conditions. Avoid: dust generation, excess heat, strong oxidants. Incompatible: Oxidizing agents. Haz Decomp: see sect 5

11. TOXIC INFO: RTECS#: N/A LD50/LC50: N/A.  Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. 

12. ECOLOGICAL INFO: No info. 

13.  DISPOSAL CONSIDERATIONS: Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.  RCRA P-Series: None listed. RCRA U-Series: None listed. 

14.  TRANSPORT INFO: Not regulated.

15.  REGULATORY INFO: SARA 311/312:Acute Health Hazard
Section 302 (TPQ) None of the chemicals in this product have a TPQ. 
Section 313No chemicals are reportable under Section 313. STATE is not present on state lists from CA, MN, MA, FL. 
Pa & NJ Right to Know:	3-Hydroxypyridine-2-carboxylic acid  CAS#874-24-8
California Prop.65: None of the chemicals are known to cause cancer, birth defects, or any other reproductive harm.
 
EUROPEAN/INTERNATIONAL REGULATIONS European Labeling in Accordance with EC Directives 
Hazard Symbols: XI.   WGK (Water Danger/Protection) CAS# 874-24-8: No information available. 
Canada - DSL/NDSL None of the chemicals in this product are listed on the DSL or NDSL list. 
Canada - WHMIS This product has a WHMIS classification of D2B. Canadian Ingredient Disclosure List 

16. DISCLAIMER INFO: DUDLEY CORPORATION provides the information herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this.  Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. DUDLEY CORPORATION makes no representations or warranties, either expressed or implied, including without limitation and warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, DUDLEY CORPORATION will not be responsible for damages resulting from the use of or reliance upon this information.