DIETHYL SAFRAMINE 

Material Safety Data Sheet
         Emergency Telephone Number: CHEMTREC 1-800-424-9300
For Information call: DUDLEY 732-886-3100       

        DUDLEY CORPORATION        
        	  125 Kenyon Drive	
        Lakewood, New Jersey 08701

Effective Date:  February 5, 2010

1. PRODUCT IDENTIFICATION:

Synonyms:   C.I. 50206; 3-Amino-7-[diethylamino]-5-phenyl phenazium chloride
CAS No.:  4569-86-2
Molecular Weight:  378.91 
Chemical Formula:  C22H23ClN4

2. COMPOSITION, INFORMATION ON INGREDIENTS:

Chemical Name 		CAS No.		Percent		Hazardous
Diethyl Saframine 	4569-86-2		90-100%	      No	 		 			 	
3.HAZARDS IDENTIFICATION:

Emergency Overview
Appearance: Dark greenish powder. CAUTION!     May cause eye and skin irritation. May cause respiratory and digestive tract irritation. The toxicological properties of this material have not been fully investigated.  
Target Organs: 

Potential Health Effects

Eyes:  Avoid contact with eyes
Skin:  May cause skin irritation
Ingestion:    May be harmful if swallowed
Inhalation:  May cause irritation of the respiratory tract.
Chronic:

4. FIRST AID MEASURES:

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. 
Skin: In case of contact, flush skin with plenty of water for at least 15 minutes while removing contaminated clothes and shoes. Get medical attention if irritation develops or persists.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls water or milk to drink. Do NOT induce vomiting. NEVER give anything by mouth to an unconscious person. Get medical attention if irritation or symptoms appear.
Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician: Treat symptomatically and supportively.
5. FIRE FIGHTING MEASURES:
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH approved or equivalent, and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.  Runoff from fire control or dilution water may cause pollution.		 Extinguishing Media: In case of fire use water spray to cool fire expose containers.  Use water spray, dry chemical, Carbon dioxide, or appropriate foam. Use agent most appropriate to extinguish fire.
Flash Point: Not available.
Auto-ignition Temperature: Not available.
Explosion Limits, Lower: Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 1; Flammability: 1; Instability: 0.

6. ACCIDENTAL RELEASE MEASURES: 
General Information: Use proper personal protective equipment as indicated in Section 8. 
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. 

7. HANDLING AND STORAGE: 
Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. 
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

8. EXPOSURE CONTROLS, PERSONAL PROTECTION: 
Engineering Controls: 
Facilities storing or utilizing this material should be equipped with an eyewash facility and safety shower. Use adequate ventilation to keep airborne concentrations low.

Exposure Limits

Chemical Name			ACGIH		NIOSH		OSHA - Final PEL’s
Diethyl Saframine		None listed 	None listed	None listed		 
OSHA Vacated PELs: Diethyl Saframine: No OSHA Vacated PELs are listed for this chemical. 

Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. 
Skin: Wear appropriate protective gloves to prevent skin exposure. 
Clothing: Wear appropriate protective clothing to prevent skin exposure. 
Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. 

9. PHYSICAL AND CHEMICAL PROPERTIES:
Physical State:  Powder
Appearance:  Dark greenish
Odor:  Not available.
Freezing/Melting Point:  285° C  
pH:  Not available.
Vapor Pressure (mm Hg):  Not available.  
Vapor Density (Air = 1):  Not available. 
Evaporation Rate:  Not available.
Viscosity:   Not available.
Boiling Point:  Not available.
Decomposition Temperature:  Not available. 
Solubility:   Not available.
Specific Gravity/Density:  Not available.

10. STABILITY AND REACTIVITY: 
Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. 
Conditions to Avoid:  Exposure to air or moisture over prolonged periods.
Incompatibilities with Other Materials:  Strong oxidizing agents.
Hazardous Decomposition Products:  Carbon monoxide, Carbon dioxide, Nitrogen oxides, Hydrogen chloride gas.
Hazardous Polymerization:  Has not been reported.

11. TOXICOLOGICAL INFORMATION: 
RTECS:
CAS#4569-86-2:  Not available.  
LD50/LC50:
CAS# 4569-86-2:  Not available. 
Carcinogenicity: CAS#4569-86-2: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. 
Epidemiology: No information available.
Teratogenicity:  No information available.
Reproductive Effects: No information available.
Neurotoxicity:  No information available.
Mutagenicity:  No information available.
Other Studies: No data available.

12. ECOLOGICAL INFORMATION: 
Environmental Fate: No information available.
Environmental Toxicity: No data available.

13. DISPOSAL CONSIDERATIONS: 
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. 
RCRA P-Series: None listed. 
RCRA U-Series: None listed. 

14. TRANSPORT INFORMATION: 

Not regulated.

15. REGULATORY INFORMATION:
US FEDERAL 
TSCA 
CAS#4569-86-2 is not listed on the TSCA inventory. 
Health & Safety Reporting List 
None of the chemicals are on the Health & Safety Reporting List. 
Chemical Test Rules 
None of the chemicals in this product are under a Chemical Test Rule. 
Section 12b 
None of the chemicals are listed under TSCA Section 12b. 
TSCA Significant New Use Rule 
None of the chemicals in this material have a SNUR under TSCA. 
SARA 
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ. 
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313 
No chemicals are reportable under Section 313. 
Clean Air Act 
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. 
Clean Water Act 
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. 
OSHA 
None of the chemicals in this product are considered highly hazardous by OSHA. 
STATE 
CAS#4569-86-2 is not present on state lists from CA, PA, MA, MN, FL, or NJ. 
California Prop 65: No Significant Risk Level: None of the chemicals in this product are listed. 

EUROPEAN/INTERNATIONAL REGULATIONS 
European Labeling in Accordance with EC Directives 
Hazardous Symbols: Not available.
Risk Phrases: Not available.
Safety Phrases: Not available.
WGK (Water Danger/Protection) CAS#4569-86-2:  No information available. 
Canada - DSL/NDSL CAS#4569-86-2 is not listed on Canada’s DSL List. 
Canada – WHMIS  WHMIS:  Not available.
CAS#4569-86-2 is not listed on Canada’s Ingredient Disclosure List. 
Exposure Limits

16. DISCLAIMER INFORMATION:
DISCLAIMER

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DUDLEY CORPORATION provides the information herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this.  Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. DUDLEY CORPORATION makes no representations or warranties, either expressed or implied, including without limitation and warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, DUDLEY CORPORATION will not be responsible for damages resulting from the use of or reliance upon this information.   
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