5-BROMO-2-NITROPYRIDINE

Safety Data Sheet
Emergency Telephone Number: CHEMTREC 1-800-424-9300       For Information call: DUDLEY 732-886-3100       
      DUDLEY CORPORATION
           	125 Kenyon Drive
       				         	 Lakewood, New Jersey 08701
Effective Date: January 1, 2015	

1. PRODUCT IDENTIFICATION: 
Synonyms:  None     CAS No.: 39856-50-3	Molecular Weight:  202.99g/mol Chemical Formula: C5H3BrN2O2

2. HAZARDS IDENTIFICATION: 

GHS Classification: Skin irritation (Category 2)	Eye irritation (Category 2A)		
			Specific target organ toxicity - single exposure (Category 3)
 Pictogram: 				
Signal Word:         WARNING

HAZARD STATEMENT(S): H319: Causes serious eye irritation.		H315: Causes skin irritation
H335: May cause respiratory irritation	
 	
PRECAUTIONARY STATEMENT(S) : P261: Aviod breathing dust/spray/ fume/gas/ mist/ vapors.
P264: wash skin thoroughly after handling	P271: Use only outdoors or in well-ventilated area.	
P405: Store locked up.	P280: Wear protective gloves/eye & face protection	
P302 + P352:If on skin: wash with plenty of soap & water.
P304 + P340: If inhaled: remove to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: If in Eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present & easy to do so. Continue Rinsing.	
P312: Call Poison Center or doctor/physician if you feel unwell
P321: Specific treatment (see supplemental first aid instructions)
P332 + P313: If skin irritation occurs: consult physician  P337+P313: If eye irritation occurs: consult physician
P362: Take off contaminated clothing and wash before reuse.
P403 + P233: Store in a well ventilated place. Keep container tightly closed.
P501: Dispose of contents/container to an approved waste disposal plant.

HMIS Classification: Health hazard  2, Flammability   0,  Physical hazards   0			
NFPA Rating: Health hazard  2, Fire     0, Reactivity hazard   0

Potential Health Effects
Eye: Risk of serious damage to eyes.	Skin: Harmful in contact with skin. 
Ingestion: Harmful if swallowed. 		Inhalation: Harmful by inhalation. 

3. COMPOSITION / INFORMATION ON INGREDIENTS: 
Chemical Name			 CAS No.	 	Percent		
5-Bromo-2-nitropyridine	                39856-50-3               99%                  

4. FIRST AID MEASURES: 
Eyes: In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
Skin:. Rinse with plenty of soap & water and seek medical advice.
Ingestion: Do not induce vomiting without medical advice. Rinse with water. Consult physician.
Inhalation: Move to fresh air.  Consult a physician.
Notes to Physician: Treat symptomatically and supportively. 

5. FIRE FIGHTING MEASURES:
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH approved or equivelent, and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.  
Special Hazard Arising: Carbon & nitrogen oxides, Hydrogen bromide gas
Extinguishing Media: Use water spray, dry chemical, Carbon dioxide, or alcohol-resistant foam.
Flash Point: Not available. Autoignition Temperature: Not available. Explosion Limits: Not available.

6. ACCIDENTAL RELEASE MEASURES: 
General Information: Use proper personal protective equipment as indicated in Section 8. 
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. 

7. HANDLING AND STORAGE: 
Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Avoid prolonged or repeated exposure. Keep container tightly closed.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.   

8. EXPOSURE CONTROLS, PERSONAL PROTECTION: 
Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and safety shower. Use adequate ventilation to keep airborne concentrations low.
Chemical Name			ACGIH		NIOSH		OSHA - Final / Vacated PEL’s
5-Bromo-2-nitropyridine		None listed	None listed	None listed

Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. 
Skin: Wear appropriate protective gloves to prevent skin exposure. 
Clothing: Wear appropriate protective clothing to prevent skin exposure. 
Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. 

9. PHYSICAL AND CHEMICAL PROPERTIES:
Physical State: solid	Appearance: Yellow powder.	Odor: Not available Melting Point: 148-150˚C
pH: Not available.	Vapor Pressure: Not available.	Vapor Density: Not available.
Evaporation Rate: Not available.	Viscosity: Not available.	Boiling Point: Not available.
Decomposition Temperature: Not available. Solubility: Not available. Density: Not available. 

10. STABILITY AND REACTIVITY: 
Chemical Stability: Stable at room temp. in closed containers under normal storage and handling conditions. 
Conditions to Avoid: Incompatible materials.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: see section 5

11. TOXICOLOGICAL INFORMATION: 
RTECS: CAS# 39856-50-3	LD50/LC50: CAS# 39856-50-3 Not available.
Carcinogenicity: CAS# 39856-50-3: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. 
Epidemiology: No data available. 	Teratogenicity: No data available.
Reproductive Effects: No data available.	Neurotoxicity: No data available.
Mutagenicity: No data available.		Other Studies: No data available.

12. ECOLOGICAL INFORMATION: Environmental Fate/Toxicity: No information available.

13. DISPOSAL CONSIDERATIONS: 
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed. 

14. TRANSPORT INFORMATION: Not regulated.

15. REGULATORY INFORMATION:US FEDERAL 
SARA 311/312: Acute health hazard
CERCLA Haz. Substances & corresponding RQsNone of the chemicals in material have an RQ. 
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313 No chemicals are reportable under Section 313. 
STATE CAS# 39856-50-3 is not present on state lists from CA, MN, MA, FL. 
Pennsylvania Right to Know:	5-Bromo-2-nitropyridine  CAS#39856-50-3
New Jersey Right to Know:	5-Bromo-2-nitropyridine  CAS#39856-50-3
California Prop.65 components: None of the chemicals are known to cause cancer, birth defects, or any other reproductive harm.

EUROPEAN/INTERNATIONAL REGULATIONS European Labeling in Accordance with EC Directives 
Hazardous Symbols: XI -  Irritant
WGK (Water Danger/Protection) CAS# 39856-50-3: No information available. 
Canada - DSL/NDSLCAS# 39856-50-3 is not listed on Canada’s DSL or NDSL  Lists. 
Canada - WHMISCAS# 39856-50-3 is not listed on Canada’s Ingredient Disclosure List. 

16. DISCLAIMER INFORMATION:
DUDLEY CORPORATION provides the information herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this.  Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. DUDLEY CORPORATION makes no representations or warranties, either expressed or implied, including without limitation and warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, DUDLEY CORPORATION will not be responsible for damages resulting from the use of or reliance upon this information.