BRILLIANT GREEN 

Safety Data Sheet
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      DUDLEY CORPORATION
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Effective Date: January 1, 2025	
1. PRODUCT ID: Syn:  Emerald green, Solid green JO, Ethyl Green, Diamond green, Basic Green 1, Malachite green G, Astradiamant green GX CAS No.: 633-03-4 E-C No.:211-190-1 Weight:  482.63g/mol Formula: C27H34N2O4S

2. HAZARDS ID: GHS: Acute toxicity, Oral (Category 4)     Skin irritation (Cat. 2)  Serious Eye Damage (Cat 1)	
Skin sensitization (Cat 1)	Acute aquatic hazard (Cat1)	Chronic Aquatic hazard (Cat1)	
 Pictogram: 				        
Signal Word:         DANGER
HAZARD STATEMENT(S): H302: Harmful if swallowed. H315: Causes skin irritation. H317: May cause an allergic skin reaction. 	H318: Causes serious eye damage. H410: Very toxic to aquatic life with long lasting effects. 
PRECAUTIONARY STATEMENT(S): P261: Avoid breathing dust. P264: Wash skin thoroughly after handling P270: Do not drink, eat, smoke, when using this product. P272: Contaminated work clothing must not be allowed out of the workplace. P273: Avoid release into the environment.  P280: Wear protective gloves/eye & face protection P330: Rinse mouth P301 + P312: If swallowed: Call Poison Center or doctor/physician if you feel unwell. P305 + P351 + P338: If in Eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present & easy to do so. Continue rinsing.  P333 + P313: If skin irritation occurs: consult physician. P362: Take off contaminated clothing and wash before reuse. P391: Collect spillage. P501: Dispose of contents/container to an approved waste disposal plant. P310: Remove contact lenses, 

HMIS: Health hazard 2, Flammability 0,  Physical hazards   0			
NFPA Rating: Health hazard 2, Fire 0, Reactivity hazard   0
2.3: Other Hazards: none

3. COMPOSITION: 
Chemical Name			 CAS No.	 		
Brilliant Green	                		633-03-4               

4. FIRST AID:  Inhalation: Move to fresh air.  Eyes: Rinse immediately with plenty of water.  Skin: Rinse with plenty of soap & water. Ingestion: Do not induce vomiting without medical advice. Rinse with water. Consult physician.
Physician: Treat symptomatically and supportively. 

5. FIRE FIGHTING: Info: Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH, & full PPE. Irritating & highly toxic gases may be generated by thermal decomp or combustion.  Runoff from fire control or dilution water may cause pollution.  Hazards: Carbon, nitrogen & sulfur oxides. Extinguishing: Use water spray, dry chem, Carbon dioxide, or alcohol-resistant foam. 

6. ACCIDENTAL RELEASE:  Info: Use proper PPE as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. 

7. HANDLING & STORAGE: Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation.  Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.  Wash clothing before reuse. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatibles.   

8. EXPOSURE CONTROLS: Facilities storing or utilizing this material should be equipped with an eyewash facility and safety shower. Use adequate ventilation to keep airborne concentrations low.
Chemical Name			ACGIH		NIOSH		OSHA - Final & Vacated PEL’s
Brilliant Green 			None listed	None listed	None listed

PPE: Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. 0.11 mm thick nitrile Clothing: Wear appropriate protective clothing to prevent skin exposure.
 
Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. 

9. PHYSICAL & CHEM: Appearance: Yellow green to dark green Melting Point: 210˚C (410˚F

10. STABILITY & REACTIVITY: Avoid: Incompatible, moisture. Stability: Stable at room temp. in closed containers under normal storage/handling. Incompatibilities: Strong oxidizing agents, reducing agents. Haz Decomp: See sec 5

11. TOXICOLOGICAL INFO: RTECS: BP6825000 LD50/LC50: LD50 Oral – rat – 313 mg/kg:  Skin corrosion/irritation:  Skin – rabbit – no skin irritation. Serious eye damage/eye irritation:  Eyes – rabbit – Moderate eye irritation
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. 

12. ECOLOGICAL INFO: Environmental Fate/Toxicity: No information available.

13. DISPOSAL CONSIDERATIONS: Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. 
RCRA P-Series: None listed. RCRA U-Series: None listed. 

14. TRANSPORT INFO: Not regulated.

15. REGULATORY INFO: SARA 311/312: Acute Health Hazard
CERCLA Haz. Substances & corresponding RQ/TPQs None of the chemicals in this material have an RQ/TPQ. 
Section 313 No chemicals are reportable under Section 313. 

STATE CAS# 633-03-4 is not present on state lists from CA, MN, MA, FL. 
Pa Right to Know:	[4-[4-(Diethylamino)benzhydrylene]cyclohexa-2,5-dien-1-
ylidene]diethylammonium hydrogen sulphate  CAS#633-03-4  Revision: 04/24/93
NJ Right to Know:	[4-[4-(Diethylamino)benzhydrylene]cyclohexa-2,5-dien-1-
ylidene]diethylammonium hydrogen sulphate  CAS#633-03-4  Revision: 04/24/93
Mass Right to Know:  [4-[4-(Diethylamino)benzhydrylene]cyclohexa-2,5-dien-1-
ylidene]diethylammonium hydrogen sulphate  CAS#633-03-4  Revision: 04/24/93
California Prop.65 components: None of the chemicals are known to cause cancer, birth defects, or any other reproductive harm.

16. DISCLAIMER INFO: DUDLEY CORPORATION provides the information herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this.  Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. DUDLEY CORPORATION makes no representations or warranties, either expressed or implied, including without limitation and warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, DUDLEY CORPORATION will not be responsible for damages resulting from the use of or reliance upon this information.