BISMUTH TRIBROMOPHENATE

     Safety Data Sheet 
Emergency Telephone Number: CHEMTREC 1-800-424-9300        For Information call: DUDLEY 732-886-3100       
					     DUDLEY CORPORATION        
         	          125 Kenyon Drive	
      Lakewood, New Jersey 08701
                                                                                          Effective Date: January 1, 2024

1. PRODUCT ID: CAS No.: 5175-83-7   Weight: 1198.36 Formula: (C6H2Br3O)2BiOH*Bi2O3
Syn: Bismuth tribromophenol; Tris (2,4,6-tribromophenoxy)bismuthine; Tribromophenol bismuth; xeroform

2. HAZARDS ID:   GHS Classification: Not GHS Classified 
HMIS Classification: Health hazard  1, Flammability   0,  Physical hazards   0			
NFPA Rating: Health hazard  0, Fire     0, Reactivity hazard   0

Potential Effects: Eye: May cause mild eye irritation. Skin: May cause mild skin irritation. Absorption may occur only minimally through broken skin.  Ingestion: Low toxicity. Bismuth salts are poorly absorbed. Should absorption occur, symptoms may include loss of appetite, headache, skin rashes, kidney damage, and rarely mild jaundice. 
Inhalation:  May cause mild irritation to mucous membranes. Chronic Exposure: Repeated or prolonged ingestion may cause a “bismuth line”, black spots on the gums, foul breath, and salivation. 
2.3: Other Hazards: none
 
3. COMPOSITION, INFO ON INGREDIENTS:
Chemical Name 			CAS No.			Percent			Hazardous
Bismuth Tribromophenate		5175-83-7		~50%			    No 	

4. FIRST AID: Eyes: Wash thoroughly with running water. Get medical advice if irritation develops.  
Skin: Wash exposed area with soap and water. Get medical advice if irritation develops.  Ingestion: Give several glasses of water to drink to dilute, if patient is conscious. If large amounts were swallowed, induce vomiting and get medical advice. Inhalation: Remove to fresh air. Get medical attention for breathing difficulty.  

5. FIRE FIGHTING: Info: Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH, & full PPE. During a fire, irritating and highly toxic gases may be generated by thermal decomp or combustion.  Runoff from fire control or dilution water may cause pollution. Extinguishing: Use water spray, dry chemical, Carbon dioxide, or alcohol-resistant foam. Hazards: Hydrogen bromide gas Flash Pt: N/A Auto-ignition Temp: N/A Explosion Limits: N/A

6. ACCIDENTAL RELEASE: Info: Use proper PPE as indicated in Section 8. Spills/Leaks: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal.  

7. HANDLING & STORAGE: Handling: Wash thoroughly after handling. Use adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. 

8. EXPOSURE CONTROLS: Facility storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep concentrations low. 
Chemical Name                             ACGIH                          NIOSH                    OSHA – Final/Vacated PELs
Bismuth Tribromophenate          None listed                  None listed            None listed. 

PPE: Eyes: Use chemical safety goggles. Contact lenses should not be worn when working with this material. Maintain eyewash fountain and quick-drench facilities in work area.  Skin: Wear protective gloves and clean body-covering clothing. 0.11mm nitrile Clothing: Wear appropriate protective clothing to prevent skin exposure.  Respirators: For conditions of use where exposure to the dust is apparent, a dust/mist respirator may be worn. For emergencies, a self-contained breathing apparatus may be necessary.  

9. PHYSICAL & CHEM: Appear: Yellow to yellowish-grey, tasteless powder Odor: Particular odor  pH: Neutral to moistened Litmus paper Melting Pt: 194-203˚C Solubility: Slightly soluble in water alcohol, chloroform, vegetable oils.  

10. STABILITY & REACTIVITY: Stability: Stable under ordinary conditions of use and storage below 120 C Avoid: Incompatibles, dust generation. Incompatibilities: Strong bases, Mineral acid.  Hazardous Decomp Products: see sec 5

11. TOXICOLOGICAL INFO: RTECS#: Not available   LD50/LC50: No data  

Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. 

12. ECOLOGICAL INFO: N/A 

13. DISPOSAL CONSIDERATIONS: Chemical waste generator must determine whether a discarded chemical is classified as a hazardous waste. U.S. EPA guidelines for the classification determination are listed in 40 CFR parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed RCRA U-Series: None listed.

14. TRANSPORT REGULATIONS: Not regulated.

15. REGULATORY INFO: SARA 311/312: None
SARA Section 302 Extremely Hazardous Substances None of the chemicals in this product have a TPQ/RQ.
Section 313 No chemicals are reportable under Section 313.
STATE CAS# 5175-83-7 is not present on state lists from CA, PA, MA, MN, FL, or NJ.
California No Significant Risk Level:  None of the chemicals in this product are listed.

EUROPEAN/INTERNATIONAL REGULATIONS European Labeling in Accordance with EC Directives
WGK (Water Danger/Protection) Not available.
Canada – DSL/NDSL CAS#5175-83-7 is not listed on Canada’s DSL List.
Canada – WHMIS CAS#5175-83-7:  Not available. CAS#5175-83-7 is not list on Canada’s Ingredient Disclosure List.

16. DISCLAIMER INFO: DUDLEY CORPORATION provides the information herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this.  Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. DUDLEY CORPORATION makes no representations or warranties, either expressed or implied, including without limitation and warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, DUDLEY CORPORATION will not be responsible for damages resulting from the use of or reliance upon this information.